Chemical synthesis of α-cobalt hydroxide

被引：108

作者：

Rajamathi, M

Kamath, PV ^{[1
]}

Seshadri, R

机构：

[1] Bangalore Univ, Cent Coll, Dept Chem, Bangalore 560001, Karnataka, India

[2] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India

来源：

MATERIALS RESEARCH BULLETIN | 2000年 / 35卷 / 02期

关键词：

layered compounds; chemical synthesis;

D O I：

10.1016/S0025-5408(00)00199-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Precipitation reactions using ammonia yield a novel cobalt hydroxide phase that is structurally and compositionally similar to alpha-nickel hydroxide. The use of other synthetic methods yields the well-known beta-Co(OH)(2). The slab composition, mode of anion inclusion, and thermal behavior of the hydroxides obtained by ammonia precipitation are similar to those of alpha-nickel hydroxide; however, the materials are poorly ordered. A DIFFaX simulation of the powder X-ray diffraction patterns offers the best visual march with the observed patterns for a 50% stacking disorder and a disc radius between 100 and 1000 Angstrom. (C) 2000 Elsevier Science Ltd, All rights reserved.

引用

页码：271 / 278

页数：8

共 16 条

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