Synthesis of poly(2,5-thienyleneethynylene)s by alkyne metathesis

被引：44

作者：

Zhang, W

Moore, JS ^{[1
]}

机构：

[1] Univ Illinois, Roger Adams Lab, Dept Chem, Urbana, IL 61801 USA

[2] Univ Illinois, Roger Adams Lab, Dept Mat Sci & Engn, Urbana, IL 61801 USA

来源：

MACROMOLECULES | 2004年 / 37卷 / 11期

关键词：

D O I：

10.1021/ma049371g

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The formation of high molecular weight products by the synthesis of poly(2,5-trienylene ethylene) from alkyne metathesis was discussed. Coupling reactions of diethynylated aromatics with dihalogenated arenes was performed in the synthesis process using Shrock tungsten carbyne complex as the catalyst. The PAE (poly(aryleneethnylene)s was synthesized by the polymerization reaction for the removal of alkyne byproduct. It was found that the low boiling point of 2, butyne helped the removal of the byproduct and a higher molecular weight polymer.

引用

收藏

页码：3973 / 3975

页数：3

相关论文

共 52 条

[1] REGIOSELECTIVE POLYMERIZATION OF 3-(4-OCTYLPHENYL)THIOPHENE WITH FECL3 [J].

ANDERSSON, MR ;

SELSE, D ;

BERGGREN, M ;

JARVINEN, H ;

HJERTBERG, T ;

INGANAS, O ;

WENNERSTROM, O ;

OSTERHOLM, JE .

MACROMOLECULES, 1994, 27 (22) :6503-6506

[2] POLY(N-(3-THIENYL)ALKANESULFONATES) - SYNTHESIS, REGIOREGULARITY, MORPHOLOGY, AND PHOTOCHEMISTRY [J].

ARROYOVILLAN, MI ;

DIAZQUIJADA, GA ;

ABDOU, MSA ;

HOLDCROFT, S .

MACROMOLECULES, 1995, 28 (04) :975-984

[3] Are single molecular wires conducting? [J].

Bumm, LA ;

Arnold, JJ ;

Cygan, MT ;

Dunbar, TD ;

Burgin, TP ;

Jones, L ;

Allara, DL ;

Tour, JM ;

Weiss, PS .

SCIENCE, 1996, 271 (5256) :1705-1707

[4] Poly(p-phenyleneethynylene)s by alkyne metathesis [J].

Bunz, UHF .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (12) :998-1010

[5] STAR-SHAPED TRICARBONYL(CYCLOBUTADIENE)IRON AND CYMANTRENE COMPLEXES - BUILDING-BLOCKS FOR CARBON NETS AND ORGANOMETALLIC CONSTRUCTION SETS [J].

BUNZ, UHF ;

ENKELMANN, V .

ORGANOMETALLICS, 1994, 13 (10) :3823-3833

[6]

Bunz UHF, 1999, ANGEW CHEM INT EDIT, V38, P478, DOI 10.1002/(SICI)1521-3773(19990215)38:4<478::AID-ANIE478>3.0.CO

[7]

2-K

[8] Poly(aryleneethynylene)s: Syntheses, properties, structures, and applications [J].

Bunz, UHF .

CHEMICAL REVIEWS, 2000, 100 (04) :1605-1644

[9] SYNTHESIS OF ARYL-SUBSTITUTED AND VINYL-SUBSTITUTED ACETYLENE DERIVATIVES BY USE OF NICKEL AND PALLADIUM COMPLEXES [J].

CASSAR, L .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 93 (02) :253-257

[10] REGIOCONTROLLED SYNTHESIS OF POLY(3-ALKYLTHIOPHENES) MEDIATED BY RIEKE ZINC - THEIR CHARACTERIZATION AND SOLID-STATE PROPERTIES [J].

CHEN, TA ;

WU, XM ;

RIEKE, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (01) :233-244

← 1 2 3 4 5 6 →