Solution-Processed Organic Solar Cells Based on Dialkylthiol-Substituted Benzodithiophene Unit with Efficiency near 10%

被引:695
作者
Kan, Bin
Zhang, Qian
Li, Miaomiao
Wan, Xiangjian
Ni, Wang
Long, Guankui
Wang, Yunchuang
Yang, Xuan
Feng, Huanran
Chen, Yongsheng [1 ]
机构
[1] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Coll Chem, Inst Polymer Chem,Key Lab Funct Polymer Mat, Tianjin 300071, Peoples R China
关键词
HIGH-PERFORMANCE; SMALL MOLECULES; RECOMBINATION; PHOTOVOLTAICS; MORPHOLOGY; POLYMERS; DESIGN;
D O I
10.1021/ja509703k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A small molecule named DR3TSBDT with dialkylthiol-substituted benzo[1,2-b:4,5-b']dithiophene (BDT) as the central unit was designed and synthesized for solution-processed bulk-heterojunction solar cells. A notable power conversion efficiency of 9.95% (certified 9.938%) has been achieved under AM 1.5G irradiation (100 mW cm(-2)), with an average PCE of 9.60% based on 50 devices.
引用
收藏
页码:15529 / 15532
页数:4
相关论文
共 36 条
[1]   Molecular Design and Ordering Effects in π-Functional Materials for Transistor and Solar Cell Applications [J].
Beaujuge, Pierre M. ;
Frechet, Jean M. J. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (50) :20009-20029
[2]   Influence of blend microstructure on bulk heterojunction organic photovoltaic performance [J].
Brabec, Christoph J. ;
Heeney, Martin ;
McCulloch, Iain ;
Nelson, Jenny .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (03) :1185-1199
[3]   High Performance Photovoltaic Applications Using Solution-Processed Small Molecules [J].
Chen, Yongsheng ;
Wan, Xiangjian ;
Long, Guankui .
ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (11) :2645-2655
[4]   Design and Synthesis of Molecular Donors for Solution-Processed High-Efficiency Organic Solar Cells [J].
Coughlin, Jessica E. ;
Henson, Zachary B. ;
Welch, Gregory C. ;
Bazan, Guillermo C. .
ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (01) :257-270
[5]   Improvement of open-circuit voltage and photovoltaic properties of 2D-conjugated polymers by alkylthio substitution [J].
Cui, Chaohua ;
Wong, Wai-Yeung ;
Li, Yongfang .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (07) :2276-2284
[6]   25th Anniversary Article: A Decade of Organic/Polymeric Photovoltaic Research [J].
Dou, Letian ;
You, Jingbi ;
Hong, Ziruo ;
Xu, Zheng ;
Li, Gang ;
Street, Robert A. ;
Yang, Yang .
ADVANCED MATERIALS, 2013, 25 (46) :6642-6671
[7]  
Guo XG, 2013, NAT PHOTONICS, V7, P825, DOI [10.1038/nphoton.2013.207, 10.1038/NPHOTON.2013.207]
[8]  
He ZC, 2012, NAT PHOTONICS, V6, P591, DOI [10.1038/NPHOTON.2012.190, 10.1038/nphoton.2012.190]
[9]   Bulk Heterojunction Solar Cells: Morphology and Performance Relationships [J].
Huang, Ye ;
Kramer, Edward J. ;
Heeger, Alan J. ;
Bazan, Guillermo C. .
CHEMICAL REVIEWS, 2014, 114 (14) :7006-7043
[10]   Alkylthio-Substituted Polythiophene: Absorption and Photovoltaic Properties [J].
Huo, Lijun ;
Yi Zhou ;
Li, Yongfang .
MACROMOLECULAR RAPID COMMUNICATIONS, 2009, 30 (11) :925-931