Pronounced axial thiolate ligand effect on the reactivity of high-valent ore-iron porphyrin intermediate

被引：70

作者：

Urano, Y ^{[1
]}

Higuchi, T ^{[1
]}

Hirobe, M ^{[1
]}

Nagano, T ^{[1
]}

机构：

[1] UNIV TOKYO,GRAD SCH PHARMACEUT SCI,BUNKYO KU,TOKYO 113,JAPAN

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1997年 / 119卷 / 49期

关键词：

D O I：

10.1021/ja972892h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：12008 / 12009

页数：2

共 19 条

[1] MODEL STUDIES ON THE ACTIVE-SITE OF CYTOCHROME-P-450 - AN FEII PORPHYRIN CARRYING A STRAPPED THIOLATE LIGAND [J].

BATTERSBY, AR ;

HOWSON, W ;

HAMILTON, AD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (21) :1266-1268

[2] ELEMENTARY ELECTRONIC EXCITATIONS AND THE MECHANISM OF CYTOCHROME-P450 [J].

CHAMPION, PM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (09) :3433-3434

[3] MERCAPTAN-TAIL PORPHYRINS - SYNTHETIC ANALOGS FOR THE ACTIVE-SITE OF CYTOCHROME-P-450 [J].

COLLMAN, JP ;

GROH, SE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (05) :1391-1403

[4] PROBING STRUCTURE-FUNCTION RELATIONS IN HEME-CONTAINING OXYGENASES AND PEROXIDASES [J].

DAWSON, JH .

SCIENCE, 1988, 240 (4851) :433-439

[5]

DEMONTELLANO PRO, 1995, CYTOCHROME P450

[6] A PRONOUNCED AXIAL LIGAND EFFECT ON THE REACTIVITY OF OXOIRON(IV) PORPHYRIN CATION RADICALS [J].

GROSS, Z ;

NIMRI, S .

INORGANIC CHEMISTRY, 1994, 33 (09) :1731-1732

[7] REACTIVE IRON PORPHYRIN DERIVATIVES RELATED TO THE CATALYTIC CYCLES OF CYTOCHROME-P-450 AND PEROXIDASE - STUDIES OF THE MECHANISM OF OXYGEN ACTIVATION [J].

GROVES, JT ;

WATANABE, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (25) :8443-8452

[8]

HARADA N, 1984, J BIOL CHEM, V259, P3005

[9] SYNTHESIS OF A HIGHLY STABLE IRON PORPHYRIN COORDINATED BY ALKYLTHIOLATE ANION AS A MODEL FOR CYTOCHROME-P-450 AND ITS CATALYTIC ACTIVITY IN O-O BOND-CLEAVAGE [J].

HIGUCHI, T ;

UZU, S ;

HIROBE, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (19) :7051-7053

[10] HETEROLYTIC O-O BOND-CLEAVAGE OF PEROXY ACID AND EFFECTIVE ALKANE HYDROXYLATION IN HYDROPHOBIC SOLVENT MEDIATED BY AN IRON PORPHYRIN COORDINATED BY THIOLATE ANION AS A MODEL FOR CYTOCHROME-P-450 [J].

HIGUCHI, T ;

SHIMADA, K ;

MARUYAMA, N ;

HIROBE, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (16) :7551-7552

← 1 2 →