Enhanced Photovoltaic Performance by Modulating Surface Composition in Bulk Heterojunction Polymer Solar Cells Based on PBDTTT-C-T/PC71BM

被引:205
作者
Guo, Xia [1 ,4 ]
Zhang, Maojie [1 ]
Ma, Wei [2 ]
Ye, Long [1 ,4 ]
Zhang, Shaoqing [1 ]
Liu, Shengjian [3 ]
Ade, Harald [2 ]
Huang, Fei [3 ]
Hou, Jianhui [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
[2] N Carolina State Univ, Dept Phys, Raleigh, NC 27695 USA
[3] S China Univ Technol, Inst Polymer Optoelect Mat & Devices, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China
[4] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
solvent additives; morphology; polymer solar cells; surface composition; VERTICAL PHASE-SEPARATION; HIGHLY EFFICIENT; CONJUGATED POLYELECTROLYTE; MORPHOLOGY; ADDITIVES; CATHODE; IMPROVE; BLENDS; LAYER; OXIDE;
D O I
10.1002/adma.201400411
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
For the blend film of PBDTTT-C-T:PC71BM, the use of 1,8-diiodooctane as the solvent additive enriches the polymer at the top surface, so that a power conversion efficiency of 9.13% is recorded in the inverted polymer solar cell based on the blend, which is much higher than that of the device with conventional structure. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4043 / 4049
页数:7
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