Polymer electrolytes comprising organometallic compounds

被引：11

作者：

Florjanczyk, Z ^{[1
]}

Zygadlo-Monikowska, E ^{[1
]}

Bzducha, W ^{[1
]}

机构：

[1] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland

来源：

ELECTROCHIMICA ACTA | 2000年 / 45卷 / 8-9期

关键词：

poly(ethylene oxide); composite polyelectrolytes; inorganic fillers; organoaluminum compounds; ionic conductivity;

D O I：

10.1016/S0013-4686(99)00382-5

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Composite polymeric electrolytes based on PEO complexes and ethyl aluminum alkoxides have been studied. The addition of the aluminum compounds causes a considerable reduction in the PEO crystalline phase content and provides very good mechanical and thermal stability up to 140 degrees C. The glass transition temperatures of blends are low, falling within the - 64 to - 29 degrees C range. The ionic conductivity of such systems reaches the value of 10(-5) S cm(-1) at ambient temperature and that of 10(-3) S cm(-1) at 60-70 degrees C. Impedance studies show that these systems form a passive layer with a lithium electrode, which protects this electrode from corrosion processes. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：1203 / 1209

页数：7

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