Switching catalytic reaction conducted in pore void of mesoporous material by redox gate control

被引：55

作者：

Fujiwara, Masahiro

Terashima, Shigeki

Endo, Yasuko

Shiokawa, Kumi

Ohue, Hiroyoshi

机构：

[1] Natl Inst Adv Ind Sci & Technol, Kansai Ctr, Osaka 5638577, Japan

[2] Osaka Inst Technol, Asahi Ku, Osaka 5358585, Japan

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 44期

关键词：

D O I：

10.1039/b610444d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A molecular gate attached on the pore outlet of a mesoporous material, which is opened and closed by redox system of thiol groups, effectively switched the progress of a catalytic reaction promoted by the acidic site in the pore void.

引用

页码：4635 / 4637

页数：3

共 36 条

[1] Dynamics, flow motion and nanopore effect of molecules present in the MCM-41 nanopores - An overview [J].

Anandan, S ;

Okazaki, M .

MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 87 (02) :77-92

[2] Influences of material characteristics on ibuprofen drug loading and release profiles from ordered micro- and mesoporous silica matrices [J].

Andersson, J ;

Rosenholm, J ;

Areva, S ;

Lindén, M .

CHEMISTRY OF MATERIALS, 2004, 16 (21) :4160-4167

[3] Reversal by dithiothreitol treatment of the block in murine leukemia virus maturation induced by disulfide cross-linking [J].

Campbell, S ;

Oshima, M ;

Mirro, J ;

Nagashima, K ;

Rein, A .

JOURNAL OF VIROLOGY, 2002, 76 (19) :10050-10055

[4] Toward the development of ionically controlled nanoscopic molecular gates [J].

Casasús, R ;

Marcos, MD ;

Martínez-Máñez, R ;

Ros-Lis, JV ;

Soto, J ;

Villaescusa, LA ;

Amorós, P ;

Beltrán, D ;

Guillem, C ;

Latorre, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (28) :8612-8613

[5] Inclusion of ibuprofen in mesoporous templated silica:: drug loading and release property [J].

Charnay, C ;

Bégu, S ;

Tourné-Péteilh, C ;

Nicole, L ;

Lerner, DA ;

Devoisselle, JM .

EUROPEAN JOURNAL OF PHARMACEUTICS AND BIOPHARMACEUTICS, 2004, 57 (03) :533-540

[6] DITHIOTHREITOL NEW PROTECTIVE REAGENT FOR SH GROUPS [J].

CLELAND, WW .

BIOCHEMISTRY, 1964, 3 (04) :480-&

[7] Ordered mesoporous and microporous molecular sieves functionalized with transition metal complexes as catalysts for selective organic transformations [J].

De Vos, DE ;

Dams, M ;

Sels, BF ;

Jacobs, PA .

CHEMICAL REVIEWS, 2002, 102 (10) :3615-3640

[8] Control of molecular transport through stimuli-responsive ordered mesoporous materials [J].

Fu, Q ;

Rao, GVR ;

Ista, LK ;

Wu, Y ;

Andrzejewski, BP ;

Sklar, LA ;

Ward, TL ;

López, GP .

ADVANCED MATERIALS, 2003, 15 (15) :1262-+

[9] Preparation of an MCM-41/Nafion® composite material;: a selective catalyst for α-methylstyrene dimerization [J].

Fujiwara, M ;

Kuraoka, K ;

Yazawa, T ;

Xu, Q ;

Tanaka, M ;

Souma, Y .

CHEMICAL COMMUNICATIONS, 2000, (16) :1523-1524

[10] Stimuli-responsive controlled-release delivery system based on mesoporous silica nanorods capped with magnetic nanoparticles [J].

Giri, S ;

Trewyn, BG ;

Stellmaker, MP ;

Lin, VSY .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (32) :5038-5044

← 1 2 3 4 →