The phenylthiocyclopropylsilyl group: a useful latent hydroxy group

被引：10

作者：

Angelaud, R

Landais, Y ^{[1
]}

机构：

[1] Univ Lausanne, Coll Propedeut, Inst Organ Chem, CH-1015 Lausanne, Switzerland

[2] Univ Bordeaux 1, Chim Organ & Organomet Lab, F-33405 Talence, France

来源：

TETRAHEDRON | 2000年 / 56卷 / 14期

关键词：

silicon and compounds; Pummerer reactions; sulfoxides; oxidation;

D O I：

10.1016/S0040-4020(00)00112-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The alpha-dimethyl(1-phenylthio)cyclopropylsilyl group was used as a new masked hydroxy group. Three procedures have been devised to allow the oxidation of this silicon group in the presence of various functionalities. The desired alcohols are obtained in high yields with retention of configuration at the carbon centre. (C) 2000 Elsevier Science Ltd. All rights reserved.

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页码：2025 / 2036

页数：12

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