A novel 3D hybrid architecture based on (H2O)6 encircling Cu4I4-O-Cu4I4 cluster and hexanuclear Cu6(datrz)6 ring

被引：40

作者：

Zhai, Quan-Guo ^{[1
]}

Lu, Can-Zhong ^{[1
]}

Chen, Shu-Mei ^{[1
]}

Xu, Xin-Jiang ^{[1
]}

Yang, Wen-Bin ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 08期

基金：

中国国家自然科学基金;

关键词：

hybrid organic-inorganic materials; CuI; 1,2,4-triazole; solvothermal synthesis;

D O I：

10.1016/j.inoche.2006.04.033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of ligand datrz (3,5-diamino-1,2,4-triazole) with CuI in 1: 1 ethanol and water mixed solvent under solvothermal condition gives a novel three-dimensional hybrid solid, [(H3O)(2)(H2O)(4)][{Cu-6(datrz)(6)}{(Cu4I4)(2)O}] (1), which consists of unique six-connected dumb-like Cu4I4-O-Cu4I4 clusters and hexanuclear Cu-6(datrz)(6) rings. Interestingly, the chair-form water hexamer is firstly observed being interpenetrated by the inorganic cluster. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：819 / 822

页数：4

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