A novel compound with an interpenetrating 2D network structure constructed by [Mo5P2O23] and Ni-4,4′-bipyridine components:: its synthesis, characterization and magnetic behaviour

被引:65
作者
Chen, J [1 ]
Lu, SF [1 ]
Yu, RM [1 ]
Chen, ZN [1 ]
Huang, ZX [1 ]
Lu, CZ [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
关键词
D O I
10.1039/b205486h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel compound (Hbpy)(2){[(H2O)(3)Ni(bpy)(0.5)Ni(bpy)(H2O)(4)](2)[Mo5P2O23][Ni((bpy)(0.5))(2)(H2O)(2)][Mo5P2O23]).8H(2)O 1 (bpy = 4,4'-bipyridine) with an interpenetrating 2D network structure was synthesized hydrothermally and characterized by elemental analyses, IR, X-ray single crystal structure analysis and temperature-dependent magnetic susceptibility.
引用
收藏
页码:2640 / 2641
页数:2
相关论文
共 8 条
[1]   A new class of organic-inorganic hybrid materials:: Hydrothermal synthesis and structural characterization of bimetallic organophosphonate oxide phases of the Mo/Cu/O/RPO32- family [J].
Finn, RC ;
Zubieta, J .
INORGANIC CHEMISTRY, 2001, 40 (11) :2466-+
[2]   Composite solids constructed from one-dimensional coordination polymer matrices and molybdenum oxide subunits: Polyoxomolybdate clusters within [{Cu(4,4'-bpy)}(4)Mo8O26] and [{Ni(H2O)(2)(4,4'-bpy)(2)}(2)Mo8O26] and one-dimensional oxide chains in [{Cu(4,4'-bpy)}(4)Mo15O47]center dot 8H(2)O [J].
Hagrman, D ;
Zubieta, C ;
Rose, DJ ;
Zubieta, J ;
Haushalter, RC .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (08) :873-876
[3]  
Hagrman PJ, 1999, ANGEW CHEM INT EDIT, V38, P2639
[4]  
Khan MF, 1999, CHEM COMMUN, P23
[5]   ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].
KRESGE, CT ;
LEONOWICZ, ME ;
ROTH, WJ ;
VARTULI, JC ;
BECK, JS .
NATURE, 1992, 359 (6397) :710-712
[6]   MOLECULAR TECTONICS IN BIOMINERALIZATION AND BIOMIMETIC MATERIALS CHEMISTRY [J].
MANN, S .
NATURE, 1993, 365 (6446) :499-505
[7]  
OCCELLI L, 1989, ZEOLITE SYNTHESIS
[8]   TOPOCHEMISTRY OF ZEOLITES AND RELATED MATERIALS .1. TOPOLOGY AND GEOMETRY [J].
SMITH, JV .
CHEMICAL REVIEWS, 1988, 88 (01) :149-182