Geometric and electronic structure of the N/Rh(100) system by core-level photoelectron spectroscopy: Experiment and theory

被引：26

作者：

Bianchettin, Laura

Baraldi, Alessandro ^{[1
]}

de Gironcoli, S.

Lizzit, S.

Petaccia, L.

Vesselli, E.

Comelli, G.

Rosei, R.

机构：

[1] Univ Trieste, Dept Phys, Trieste, Italy

[2] Univ Trieste, Ctr Excellence Nanostruct Mat, Trieste, Italy

[3] INFM, CNR, Lab TASC, I-34012 Trieste, Italy

[4] SISSA, Scuola Int Super Studi Avanzati, I-34014 Trieste, Italy

[5] INFM, Democritos Natl Simulat Ctr, I-34014 Trieste, Italy

[6] Sincrotrone Trieste, I-34012 Trieste, Italy

来源：

PHYSICAL REVIEW B | 2006年 / 74卷 / 04期

关键词：

D O I：

10.1103/PhysRevB.74.045430

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The nitrogen interaction with Rh(100) was studied by combining high-energy resolution core level photoelectron spectroscopy and density functional calculations. Nitrogen-induced Rh3d(5/2) surface core level shifts depend on the N-Rh local geometrical configuration. The core level shifts are dominated by initial state effects and correlate strongly with the variation of the energy position of the surface atom-projected d-band center.

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页数：9

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