Loosely bonded adducts of plumbocene; Structure and solution dynamics of [(eta-C5H5)(2)Pb center dot tmeda] and [(eta-C5H5)(2)Pb center dot 4,4'-Me(2)biby] (tmeda=Me(2)NCH(2)CH(2)NMe(2),4,4'-Me(2)bipy=4,4'-dimethylbipyridine)

被引：19

作者：

Beswick, MA ^{[1
]}

Cromhout, NL ^{[1
]}

Harmer, CN ^{[1
]}

Raithby, PR ^{[1
]}

Russel, CA ^{[1
]}

Smith, JSB ^{[1
]}

Steiner, A ^{[1
]}

Wright, DS ^{[1
]}

机构：

[1] UNIV CAMBRIDGE, DEPT CHEM, CAMBRIDGE CB2 1EW, ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 16期

关键词：

D O I：

10.1039/cc9960001977

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first Lewis-base adducts of a neutral p-block group metallocene, [(eta-C5H5)(2)Pb-tmeda] 1 and [eta-C5H5)(2)Pb . 4,4'-Me(2)bipy] 2, result from the addition of tmeda and 4,4'-Me(2)bipy to [Pb(eta-C5H5)(2)] (1:1 equiv.); X-ray and solution studies reveal that the Lewis bases are only loosely associated to the Pb-II centres in these complexes.

引用

页码：1977 / 1978

页数：2

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