Metal carbonyl derivatives of 1,4-quinone and 1,4-hydroquinone

被引：14

作者：

Adams, RD ^{[1
]}

Miao, SB ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 16期

关键词：

D O I：

10.1021/ja049170s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CpMoMn(CO)5(μ-S2), 1 reacts with 1,4-benzoquinone to yield CpMoMn(CO)5(μ-S2C6H2O2), 2 containing a 1,4-quinonedithiolato ligand formed by replacing two of the hydrogen atoms on one of the C-C double bonds of 1,4-benzoquinone with sulfur atoms from the disulfido ligand in 1. Compound 2 was reduced with hydrogen to yield CpMoMn(CO)5[μ-S2C6H2(OH)2], 3 which contains a 1,4-hydroquinonedithiolato ligand. Compound 3 was reoxidized to 2 with ferrocenium hexafluorophosphate. Copyright © 2003 American Chemical Society.

引用

页码：5056 / 5057

页数：2

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