Resonant quantum tunneling in a new tetranuclear iron(III)-based single-molecule magnet

被引：73

作者：

Moragues-Cánovas, M

Rivière, P

Ricard, L

Paulsen, C

Wernsdorfer, W

Rajaraman, G

Brechin, EK

Mallah, T ^{[1
]}

机构：

[1] Univ Paris 11, CNRS, UMR 8613, Chim Inorgan Lab, F-91405 Orsay, France

[2] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

[3] Ecole Polytech, CNRS, UMR 7653, F-91128 Palaiseau, France

[4] CNRS, Ctr Rech Tres Basses Temp, F-38042 Grenoble 9, France

[5] CNRS, Lab Louis Neel, F-38042 Grenoble 9, France

来源：

ADVANCED MATERIALS | 2004年 / 16卷 / 13期

关键词：

D O I：

10.1002/adma.200306479

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One of the challenges in molecular magnetism is the preparation of molecular clusters that behave as single-molecule magnets (SMMs).([1]) Such behavior, due to the slow relaxation of the magnetization below a given temperature, may open new horizons for one-molecule information storage-even though not above liquid-helium temperature for the time being. The number of polynuclear complexes that behave as SMMs is increasing and examples of V, Mn, Fe, Ni, and Co complexes can be found in the literature.([2]) But to date, SMMs based on iron(III) are still rare.

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页码：1101 / +

页数：6

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