Cyanide sensing via metal ion removal from a fluorogenic BODIPY complex

被引:76
作者
Guliyev, Ruslan [1 ]
Buyukcakir, Onur [1 ]
Sozmen, Fazli [2 ]
Bozdemir, O. Altan [1 ]
机构
[1] Bilkent Univ, UNAM Inst Mat Sci & Nanotechnol, TR-06800 Ankara, Turkey
[2] Akdeniz Univ, Dept Chem, TR-07058 Antalya, Turkey
关键词
ENERGY-TRANSFER; FLUORESCENT-PROBE; ANION RECOGNITION; BORADIAZAINDACENE EMISSION; COLORIMETRIC DETECTION; SELECTIVE CHEMOSENSOR; PHOTODYNAMIC THERAPY; LIVING CELLS; WATER; DYES;
D O I
10.1016/j.tetlet.2009.06.117
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
We report a highly selective and sensitive reversible cyanide sensor operating in the 'turn-off-on' mode via decomplexation of Cu(II) ions from a brightly fluorescent boradiazaindacene derivative. The sensor is reversible as the emission signal originates from the dynamic equilibration of dipicolylamine-Cu(II) and tetracyanocuprate complex ions.
引用
收藏
页码:5139 / 5141
页数:3
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