Imidazolylsulfonates: Electrophilic Partners in Cross-Coupling Reactions

被引：54

作者：

Albaneze-Walker, Jennifer ^{[1
]}

Raju, Ravinder ^{[1
]}

Vance, Jennifer A. ^{[1
]}

Goodman, Andrew J. ^{[1
]}

Reeder, Michael R. ^{[1
]}

Liao, Jing ^{[1
]}

Maust, Mathew T. ^{[1
]}

Irish, Patrick A. ^{[1
]}

Espino, Peter ^{[1
]}

Andrews, David R. ^{[1
]}

机构：

[1] Schering Plough Corp, Synthet Chem Chem & Phys Sci, Union, NJ 07083 USA

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 07期

关键词：

ORGANIC FUNCTIONAL-GROUPS; IMIDAZOLE-1-SULFONATES IMIDAZYLATES; ARYL TOSYLATES; SUZUKI-MIYAURA; EFFICIENT; ESTERS; ACIDS; DERIVATIVES; REACTIVITY; METAL;

D O I：

10.1021/ol802381k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aryl imidazolylsulfonates participate as electrophilic coupling partners in palladium-mediated cross-coupling reactions. The aryl imidazolylsulfonates display good stability while maintaining good reactivity in a variety of palladium-catalyzed coupling reactions. Imidazolylsulfonates are a practical and economic alternative to triflates.

引用

页码：1463 / 1466

页数：4

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