A novel tunnel Na0.61Ti0.48Mn0.52O2 cathode material for sodium-ion batteries

被引:83
作者
Guo, Shaohua [1 ,2 ]
Yu, Haijun [1 ]
Liu, Dequan [3 ]
Tian, Wei [3 ]
Liu, Xizheng [1 ,2 ]
Hanada, Nobuko [2 ]
Ishida, Masayoshi [2 ]
Zhou, Haoshen [1 ,2 ,4 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058568, Japan
[2] Univ Tsukuba, Grad Sch Syst & Informat Engn, Tsukuba, Ibaraki 3058573, Japan
[3] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton MANA, Tsukuba, Ibaraki 3050044, Japan
[4] Nanjing Univ, Natl Lab Solid State Microstruct, Dept Energy Sci & Engn, Nanjing 210093, Jiangsu, Peoples R China
关键词
ELECTROCHEMICAL PROPERTIES; POSITIVE ELECTRODE; INTERCALATION; NA0.44MNO2; NANOWIRES; INSERTION; ENERGY; OXIDE;
D O I
10.1039/c4cc02362e
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
A novel tunnel Na0.61Ti0.48Mn0.52O2 material is explored as a cathode for sodium-ion batteries for the first time. It can deliver a reversible discharge capacity of 86 mA h g(-1) with an average voltage of 2.9 V at 0.2 C rate in a sodium half cell, exhibiting good rate capability and capacity retention at a cut-off voltage of 1.5-4 V. These results indicate that tunnel Na0.61Ti0.48Mn0.52O2 has a great potential application in large scale energy storage.
引用
收藏
页码:7998 / 8001
页数:4
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