Reactions of molecular CaF2 with [(C5Me5)TiF3] and [(C5Me4Et)TiF3]: Symbiosis between ionic solids and organometallic compounds

被引：30

作者：

Pevec, A

Demsar, A

Gramlich, V

Petricek, S

Roesky, HW

机构：

[1] UNIV LJUBLJANA,FAC CHEM & CHEM TECHNOL,SLO-1000 LJUBLJANA,SLOVENIA

[2] ETH ZURICH,LAB KRISTALLOG,CH-8092 ZURICH,SWITZERLAND

[3] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 13期

关键词：

D O I：

10.1039/a702807e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between [(C5Me5)TiF3] or [(C5Me4Et)TiF3] respectively in the presence of CaF2 (prepared in situ) resulted in the formation of [{(C5Me5)TiF3}(4)CaF2] or [{(C5Me4Et)TiF3}(4)CaF2] 2, an X-ray study of compound 2 showed it to possess a core analogous to a crown ether.

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页码：2215 / 2216

页数：2

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