Effect of pH and alkaline metal cations on the voltammetry of pt(111) single crystal electrodes in sulfuric acid solution

被引:60
作者
García, N [1 ]
Climent, V [1 ]
Orts, JM [1 ]
Feliu, JM [1 ]
Aldaz, A [1 ]
机构
[1] Univ Alicante, Dept Quim Fis, E-03080 Alicante, Spain
关键词
adsorption; cations; double layers; electrochemistry; platinum;
D O I
10.1002/cphc.200400047
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cation effects: The role of alkaline cations on the double layer structure is demonstrated (see graphic). The effect of the pH value and the nature and concentration of the cation on the voltammetric fingerprint of Pt(111) in sulfuric acid solution is pointed out.
引用
收藏
页码:1221 / 1227
页数:7
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