Coordination chemistry of organic azides and amination reactions catalyzed by transition metal complexes

被引:251
作者
Cenini, Sergio [1 ]
Gallo, Emma [1 ]
Caselli, Alessandro [1 ]
Ragaini, Fabio [1 ]
Fantauzzi, Simone [1 ]
Piangiolino, Cristiana [1 ]
机构
[1] Univ Milan, Dipartimento Chim Inorgan Met Organ & Analit, ISTM, CNR, I-20133 Milan, Italy
关键词
organic azides; transition metal complexes; homogeneous catalysis; organic synthesis; amination reactions;
D O I
10.1016/j.ccr.2005.10.002
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The interaction of organic azides with transition metal complexes will be discussed with particular attention to the coordination modes of these molecules. The stoichiometric reactions of organic azides with coordinated ligands will be considered and their use in amination reactions catalyzed by transition metal complexes will be discussed in detail. The utility of these catalytic reactions for the synthesis of organic compounds will be stressed. (c) 2005 Elsevier B.V. All rights reserved.
引用
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页码:1234 / 1253
页数:20
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