New, simple coordination compounds of Cr, Mo, and W from liquid clathrate media

被引：10

作者：

Atwood, JL

Junk, PC

May, MT

Robinson, KD

机构：

[1] Department of Chemistry, University of Missouri-Columbia, Columbia

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1996年 / 40卷 / 04期

基金：

美国国家科学基金会;

关键词：

lipid clathrates; coordination compounds; group; 6; metals;

D O I：

10.1080/00958979608024530

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of M(CO)(6) (M = Cr, Mo, W) with 18-crown-6 in the presence of H2O and HCl(g) in toluene have been explored. In each case, a liquid clathrate formed almost immediately upon reaction, from which new and unusual coordination complexes of Cr, Mo and W were isolated. The structures of [H3O+. 18-crown-6] [(CrCl4)-Cl-III(H(2)O())2(-)], [H3O+. 18-crown-6](2) [H5O2 . (Mo2Cl92-)-Cl-III] and [H3O+. 18-crown-6][(WOCl4)-O-v(H2O)(-)] were established by X-ray crystallography.

引用

收藏

页码：247 / 251

页数：5

相关论文

共 19 条

[1] ANIONIC HALOGENOPENTACARBONYLS OF CHROMIUM, MOLYBDENUM, AND TUNGSTEN [J].

ABEL, EW ;

REID, JG ;

BUTLER, IS .

JOURNAL OF THE CHEMICAL SOCIETY, 1963, (MAR) :2068-+

[2]

Atwood J.L., 1984, Inclusion Compounds, V1, P375

[3] LIQUID CLATHRATE MEDIA CONTAINING TRANSITION-METAL HALOCARBONYL ANIONS - FORMATION AND CRYSTAL-STRUCTURES OF [K+CENTER-DOT-18-CROWN-6][CR(CO)(5)CL], [H3O+CENTER-DOT-18-CROWN-6][W(CO)(5)CL], [H3O+CENTER-DOT-18-CROWN-6][W(CO)(4)CL-3], AND [H2O-CENTER-DOT-BIS-AZA-18-CROWN-6-CENTER-DOT(H+)(2)][W(CO)(4)CL-3](2) [J].

ATWOOD, JL ;

BOTT, SG ;

JUNK, PC ;

MAY, MT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 487 (1-2) :7-15

[4] SYNTHESIS OF SALTS OF THE HYDROGEN DICHLORIDE ANION IN AROMATIC SOLVENTS .2. SYNTHESES AND CRYSTAL-STRUCTURES OF [K.18-CROWN-6][CL-H-CL], [MG.18-CROWN-6][CL-H-CL]2, [H3O.18-CROWN-6][CL-H-CL], AND THE RELATED [H3O.18-CROWN-6][BR-H-BR] [J].

ATWOOD, JL ;

BOTT, SG ;

MEANS, CM ;

COLEMAN, AW ;

ZHANG, HM ;

MAY, MT .

INORGANIC CHEMISTRY, 1990, 29 (03) :467-470

[5] PREPARATION AND X-RAY STRUCTURE OF [H3O+.18-CROWN-6]-[(H5O2+)(CL-)2], A COMPOUND CONTAINING BOTH H3O+ AND H5O2+ CRYSTALLIZED FROM AROMATIC SOLUTION [J].

ATWOOD, JL ;

BOTT, SG ;

ROBINSON, KD ;

BISHOP, EJ ;

MAY, MT .

JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH, 1991, 21 (04) :459-462

[6] THE H3O+ CATION IN AROMATIC SOLVENTS - SYNTHESIS, STRUCTURE, AND SOLUTION BEHAVIOR OF [H3O+.18-CROWN-6][CL-H-CL] [J].

ATWOOD, JL ;

BOTT, SG ;

COLEMAN, AW ;

ROBINSON, KD ;

WHETSTONE, SB ;

MEANS, CM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (26) :8100-8101

[7]

ATWOOD JL, 1986, CHEM SEPARATIONS, P335

[8]

ATWOOD JL, 1988, SEPAR TECHNOL, P46

[9] COMPLEX-REACTION PRODUCT OF DIMOLYBDENUM TETRAACETATE WITH AQUEOUS HYDROCHLORIC-ACID - STRUCTURAL CHARACTERIZATION OF THE HYDRIDO-BRIDGED [MO2CL8H]3-ION, THE [MO(O)CL4(H2O)]-ION, AND AN H5O2+ION WITH AN EXCEPTIONALLY SHORT HYDROGEN-BOND [J].

BINO, A ;

COTTON, FA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (15) :4150-4154

[10] COMPLEXES OF 18-CROWN-6 WITH OXONIUM IONS DERIVED FROM TRANSITION-METAL CHLORIDES AND HYDROCHLORIC-ACID - 18-CROWN-6.H3O+.FECL4-, 18-CROWN-6.H3O+.INCL4-, (18-CROWN-6.H3O+)2.PD2CL62- [J].

CHENEVERT, R ;

CHAMBERLAND, D ;

SIMARD, M ;

BRISSE, F .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1989, 67 (01) :32-36