New, simple coordination compounds of Cr, Mo, and W from liquid clathrate media

被引：10

作者：

Atwood, JL

Junk, PC

May, MT

Robinson, KD

机构：

[1] Department of Chemistry, University of Missouri-Columbia, Columbia

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1996年 / 40卷 / 04期

基金：

美国国家科学基金会;

关键词：

lipid clathrates; coordination compounds; group; 6; metals;

D O I：

10.1080/00958979608024530

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of M(CO)(6) (M = Cr, Mo, W) with 18-crown-6 in the presence of H2O and HCl(g) in toluene have been explored. In each case, a liquid clathrate formed almost immediately upon reaction, from which new and unusual coordination complexes of Cr, Mo and W were isolated. The structures of [H3O+. 18-crown-6] [(CrCl4)-Cl-III(H(2)O())2(-)], [H3O+. 18-crown-6](2) [H5O2 . (Mo2Cl92-)-Cl-III] and [H3O+. 18-crown-6][(WOCl4)-O-v(H2O)(-)] were established by X-ray crystallography.

引用

页码：247 / 251

页数：5

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