Mesoporous Organosilicas with Acidic Frameworks and Basic Sites in the Pores: An Approach to Cooperative Catalytic Reactions

被引：163

作者：

Shylesh, Sankaranarayanapillai ^{[1
]}

Wagener, Alex ^{[1
]}

Seifert, Andreas ^{[2
]}

Ernst, Stefan ^{[1
]}

Thiel, Werner R. ^{[1
]}

机构：

[1] TU Kaiserslautern, Fachbereich Chem, Kaiserslautern, Germany

[2] TU Chemnitz, Inst Chem, Chemnitz, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 01期

关键词：

bifunctional catalysts; domino reactions; heterogeneous catalysis; mesoporous materials; silicates; ORGANIC FUNCTIONAL-GROUPS; ONE-POT SYNTHESIS; MULTIFUNCTIONAL HETEROGENEOUS CATALYST; EFFICIENT NANOPOROUS CATALYSTS; ALPHA-ALKYLATED NITRILES; NITROALDOL CONDENSATION; SILICA NANOPARTICLES; TANDEM CATALYSIS; SOLID CATALYSTS; MOLECULAR-SCALE;

D O I：

10.1002/anie.200903985

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two In one: A periodic mesoporous phenylene silica (PMO) with acidic framework walls and basic pore channels was obtained by using protecting-group techniques. This approach allows location of the acidic groups in the hydrophobic benzene layers and of the amine groups in the hydrophilic silica layers. The afunctional material is an efficient catalyst for the tandem conversion of benzaldehyde dimethyl acetal into 2-nitrovinylbenzene (see scheme). chemical equation presentation ©2010 Wiley-VCH Verlag GmbH &. Co. KGaA, Weinheim.

引用

页码：184 / 187

页数：4

共 77 条

[1] Mesoporous materials with an acidic framework and basic pores.: A successful cohabitation [J].

Alauzun, Johan ;

Mehdi, Ahmad ;

Reye, Catherine ;

Corriu, Robert J. P. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (27) :8718-8719

[2] Selective, efficient nanoporous catalysts for nitroaldol condensation: Co-placement of multiple site-isolated functional groups on mesoporous materials [J].

Anan, Abhishek ;

Sharma, Krishna K. ;

Asefa, Tewodros .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 288 (1-2) :1-13

[3] Periodic mesoporous organosilicas with organic groups inside the channel walls [J].

Asefa, T ;

MacLachlan, MJ ;

Coombs, N ;

Ozin, GA .

NATURE, 1999, 402 (6764) :867-871

[4] Novel bifunctional periodic mesoporous organosilicas, BPMOs: Synthesis, characterization, properties and in-situ selective hydroboration-alcoholysis reactions of functional groups [J].

Asefa, T ;

Kruk, M ;

MacLachlan, MJ ;

Coombs, N ;

Grondey, H ;

Jaroniec, M ;

Ozin, GA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (35) :8520-8530

[5] Periodic mesoporous organosilica incorporating a catalytically active vanadyl Schiff base complex in the framework [J].

Baleizao, C ;

Gigante, B ;

Das, D ;

Alvaro, M ;

Garcia, H ;

Corma, A .

JOURNAL OF CATALYSIS, 2004, 223 (01) :106-113

[6]

Bass J.D., 2003, ANGEW CHEM INT EDIT, V115, P5377, DOI [DOI 10.1002/ANGE.200352181, 10.1002/ange.200352181]

[7] Acid-base bifunctional and dielectric outer-sphere effects in heterogeneous catalysis: A comparative investigation of model primary amine catalysts [J].

Bass, JD ;

Solovyov, A ;

Pascall, AJ ;

Katz, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (11) :3737-3747

[8] Bifunctional surface imprinting of silica: Thermolytic synthesis and characterization of discrete thiol-amine functional group pairs [J].

Bass, JD ;

Katz, A .

CHEMISTRY OF MATERIALS, 2006, 18 (06) :1611-1620

[9] The effect of outer-sphere acidity on chemical reactivity in a synthetic heterogeneous base catalyst [J].

Bass, JD ;

Anderson, SL ;

Katz, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (42) :5219-5222

[10] Amine-functionalized periodic mesoporous organosilicas [J].

Burleigh, MC ;

Markowitz, MA ;

Spector, MS ;

Gaber, BP .

CHEMISTRY OF MATERIALS, 2001, 13 (12) :4760-4766

← 1 2 3 4 5 6 7 8 →