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Being excited by lanthanide coordination complexes: Aqua species, chirality, excited-state chemistry, and exchange dynamics

被引：820
作者：
Parker, D [1 ]
Dickins, RS [1 ]
Puschmann, H [1 ]
Crossland, C [1 ]
Howard, JAK [1 ]
机构：
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
来源：
CHEMICAL REVIEWS | 2002年 / 102卷 / 06期
关键词：
D O I：
10.1021/cr010452+
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The complexation chemistry of lanthanide ions in aqueous solutions were shown. Structural aspects of the lanthanide-water bond by a comprehensive analysis of the Cambridge Structural Database (CSD) of all published species in coordination number 9, processing between one and nine bound water molecules, focusing on q=1, 2, and 9 systems. This paper updates aspects of inter- and intramolecular exchange processes, summarizes advances in magnetic resonance spectroscopy, and reviews the developments in the excited-state chemistry of luminescent lanthanide complexes.
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页码：1977 / 2010
页数：34
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