Being excited by lanthanide coordination complexes: Aqua species, chirality, excited-state chemistry, and exchange dynamics

被引：820

作者：

Parker, D ^{[1
]}

Dickins, RS ^{[1
]}

Puschmann, H ^{[1
]}

Crossland, C ^{[1
]}

Howard, JAK ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

CHEMICAL REVIEWS | 2002年 / 102卷 / 06期

关键词：

D O I：

10.1021/cr010452+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexation chemistry of lanthanide ions in aqueous solutions were shown. Structural aspects of the lanthanide-water bond by a comprehensive analysis of the Cambridge Structural Database (CSD) of all published species in coordination number 9, processing between one and nine bound water molecules, focusing on q=1, 2, and 9 systems. This paper updates aspects of inter- and intramolecular exchange processes, summarizes advances in magnetic resonance spectroscopy, and reviews the developments in the excited-state chemistry of luminescent lanthanide complexes.

引用

收藏

页码：1977 / 2010

页数：34

相关论文

共 285 条

[21] Modulation of the water exchange rates in [Gd-DO3A] complex by formation of ternary complexes with carboxylate ligands [J].

Aime, S ;

Botta, M ;

Bruce, JI ;

Mainero, V ;

Parker, D ;

Terreno, E .

CHEMICAL COMMUNICATIONS, 2001, (01) :115-116

[22] Gd(III) complexes as contrast agents for magnetic resonance imaging: A proton relaxation enhancement study of the interaction with human serum albumin [J].

Aime, S ;

Botta, M ;

Fasano, M ;

Crich, SG ;

Terreno, E .

JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 1996, 1 (04) :312-319

[23] Relaxometric determination of the exchange rate of the coordinated water protons in a neutral Gd-III chelate [J].

Aime, S ;

Botta, M ;

Fasano, M ;

Paoletti, S ;

Terreno, E .

CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (09) :1499-1504

[24] A macromolecular Gd(III) complex as pH-responsive relaxometric probe for MRI applications [J].

Aime, S ;

Botta, M ;

Crich, SG ;

Giovenzana, G ;

Palmisano, G ;

Sisti, M .

CHEMICAL COMMUNICATIONS, 1999, (16) :1577-1578

[25] Metal complexes as allosteric effectors of human hemoglobin:: An NMR study of the interaction of the gadolinium(III) bis(m-boroxyphenylamide)diethylenetriaminepentaacetic acid complex with human oxygenated and deoxygenated hemoglobin [J].

Aime, S ;

Digilio, G ;

Fasano, M ;

Paoletti, S ;

Arnelli, A ;

Ascenzi, P .

BIOPHYSICAL JOURNAL, 1999, 76 (05) :2735-2743

[26] INCLUSION COMPLEXES BETWEEN BETA-CYCLODEXTRIN AND BETA-BENZYLOXY-ALPHA-PROPIONIC DERIVATIVES OF PARAMAGNETIC DOTA-GD(III) AND DPTA-GD(III) COMPLEXES [J].

AIME, S ;

BOTTA, M ;

PANERO, M ;

GRANDI, M ;

UGGERI, F .

MAGNETIC RESONANCE IN CHEMISTRY, 1991, 29 (09) :923-927

[27] Multinuclear and multifrequency NMR study of gadolinium(III) complexes with bis-amide derivatives of ethylenedioxydiethylenedinitrilotetraacetic acid [J].

Aime, S ;

Barge, A ;

Botta, M ;

Frullano, L ;

Merlo, U ;

Hardcastle, KI .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (19) :3435-3440

[28] GEOMETRY OF NONAAQUALANTHANOID(3+) COMPLEX IN SOLID BROMATES AND ETHYL SULFATES [J].

ALBERTSSON, J ;

ELDING, I .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (MAY13) :1460-1469

[29]

Alderighi L, 1998, EUR J INORG CHEM, P1581

[30] DESIGN AND SYNTHESIS OF MACROCYCLIC LIGANDS AND THEIR COMPLEXES OF LANTHANIDES AND ACTINIDES [J].

ALEXANDER, V .

CHEMICAL REVIEWS, 1995, 95 (02) :273-342

← 1 2 3 4 5 6 7 8 9 10 →