Lanthanide(III) solvation:: N,N'-dimethylformamide as a unidentate O-donor

被引：36

作者：

Harrowfield, JM ^{[1
]}

Skelton, BW ^{[1
]}

White, AH ^{[1
]}

Wilner, FR ^{[1
]}

机构：

[1] Univ Western Australia, Chem Discipline, Sch Biomed & Chem Sci, Crawley, WA 6009, Australia

来源：

INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 08期

关键词：

lanthanide solvation; dimethylformarnidel; crystal structures; ligand-ligand attractions;

D O I：

10.1016/j.ica.2004.01.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Structure determinations for the lanthanide (Ln) complexes [(CH3)(2)NH2][Gd(dmf)(8)](ClO4)(4), [Tb(dmf)(8)](ClO4)(3) and [Ho(dMf)(7)(OH2)](ClO4)(3) (dmf=N,N-dimethylformamide) show all three to contain an LnO(8) coordination unit of essentially square-antiprismatic geometry. The geometry of the inner coordination sphere appears to be little perturbed by quite major differences in the lattice environment of the cations. Attractive interactions between coordinated dmf molecules may be one contributor to the stability of the primary coordination sphere. (C) 2004 Published by Elsevier B.V.

引用

页码：2358 / 2364

页数：7

共 35 条

[31] PROTIC-DIPOLAR APROTIC SOLVENT EFFECTS ON RATES OF BIMOLECULAR REACTIONS [J].

PARKER, AJ .

CHEMICAL REVIEWS, 1969, 69 (01) :1-&

[32]

Rogers R. D, 1996, COMPREHENSIVE SUPRAM, V1, P315

[33] F-ELEMENT CROWN-ETHER COMPLEXES .6. INTERACTION OF HYDRATED LANTHANIDE CHLORIDES WITH 15-CROWN-5 - CRYSTALLIZATION AND STRUCTURES OF [GD(OH2)8]CL3.(15-CROWN-5) [LU(OH2)8]CL3.(15-CROWN-5) [J].

ROGERS, RD ;

KURIHARA, LK .

INORGANICA CHIMICA ACTA, 1987, 130 (01) :131-137

[34] N,N-dimethylformamide complex of aluminium(III) perchlorate [J].

Suzuki, H ;

Ishiguro, S .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1998, 54 :586-588

[35] CRYSTALLOGRAPHIC EVIDENCE FOR THE EXISTENCE OF C-H...O, C-H...N, AND C-H...C1 HYDROGEN-BONDS [J].

TAYLOR, R ;

KENNARD, O .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (19) :5063-5070

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