Desolvation and substituent effects in edge-to-face aromatic interactions

被引：48

作者：

Cockroft, Scott L. ^{[1
]}

Hunter, Christopher A. ^{[2
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 26期

基金：

英国工程与自然科学研究理事会;

关键词：

DOUBLE-MUTANT CYCLES; PI-PI-INTERACTIONS; MOLECULAR RECOGNITION; INTERMOLECULAR INTERACTIONS; ORGANIC FLUORINE; MODEL; SANDWICH; BENZENE; BALANCE;

D O I：

10.1039/b902351h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Experimental measurements of aromatic edge-to-face interaction energies in both molecular torsion balances and supramolecular zipper complexes can be reliably estimated using a simple electrostatic solvation model and alpha/beta H-bond constants.

引用

页码：3961 / 3963

页数：3

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