First total synthesis of the whole series of the antiostatins A and B

被引：85

作者：

Knott, Kerstin E. ^{[1
]}

Auschill, Stefan ^{[1
]}

Jaeger, Anne ^{[1
]}

Knoelker, Hans-Joachim ^{[1
]}

机构：

[1] Tech Univ Dresden, Dept Chem, D-01069 Dresden, Germany

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 12期

关键词：

TRANSITION-METAL-COMPLEXES; ORGANIC-SYNTHESIS; ANTIOXIDATIVE AGENTS; CONVERSION; CHEMISTRY; ACID;

D O I：

10.1039/b821039j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first synthesis of the whole antiostatin family is described by using an iron-mediated carbazole synthesis, regioselective nitration at C-4 and establishing 5-isobutyl-1-nitrobiuret as a reagent for introduction of the antiostatin B side chain at C-4.

引用

页码：1467 / 1469

页数：3

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