Cyclopentadienyl-substituted phosphaferrocenes: Synthesis of a bis(phosphaferrocene) P,P-chelate ligand

被引：62

作者：

Ganter, C ^{[1
]}

Kaulen, C ^{[1
]}

Englert, U ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 26期

关键词：

D O I：

10.1021/om9905207

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel bis(phosphaferrocene)-substituted ferrocene 4 has been prepared from the corresponding cyclopentadienide 3 and shown to act as a P,P-chelate ligand in the Mo(CO)(4) comptex 5, which was structurally characterized. Enantiomerically pure (S,S)-4 was used as ligand in the catalytic asymmetric allylic substitution.

引用

页码：5444 / 5446

页数：3

共 25 条

[1] ORGANOMETALLIC DERIVATIVES OF DIPHOSPHINOAMINES, X2PN(R)PX2 - REACTIONS WITH CARBONYL DERIVATIVES OF GROUP-6 METALS AND IRON PENTACARBONYL - THE CRYSTAL-STRUCTURES OF [MO(CO)4PHN(P(OPH)2)2] AND [W(CO)4-ISO-PRN(PPH2)2]
BALAKRISHNA, MS
PRAKASHA, TK
KRISHNAMURTHY, SS
SIRIWARDANE, U
HOSMANE, NS
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 390 (02) : 203 - 216
[2] Uncovering alternative reaction pathways taken by group 4 metallocene cations: Facile intramolecular CH activation of Cp-(dimethylamino)alkyl substituents by a methylzirconocene cation
Bertuleit, A
Fritze, C
Erker, G
Frohlich, R
[J]. ORGANOMETALLICS, 1997, 16 (13) : 2891 - 2899
[3] Functionalized pentamethylferrocenes: Synthesis, structure, and electrochemistry
Bildstein, B
Hradsky, A
Kopacka, H
Malleier, R
Ongania, KH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 540 (1-2) : 127 - 145
[4] Internally phosphine-stabilized zirconocene cations employing substituted ((diarylphosphino)methyl) cyclopentadienyl ligand systems
Bosch, BE
Erker, G
Frohlich, R
Meyer, O
[J]. ORGANOMETALLICS, 1997, 16 (25) : 5449 - 5456
[5] Brassat L, 1998, CHEM-EUR J, V4, P2148
[6] BROWN JM, 1994, TETRAHEDRON, V15, P4499
[7] A new concept for chelate ligands with planar chirality
Ganter, C
Brassat, L
Glinsbockel, C
Ganter, B
[J]. ORGANOMETALLICS, 1997, 16 (13) : 2862 - 2867
[8] Ganter C, 1998, EUR J INORG CHEM, P1163
[9] Enantiomerically pure phosphaferrocenes with planar chirality
Ganter, C
Brassat, L
Ganter, B
[J]. TETRAHEDRON-ASYMMETRY, 1997, 8 (15) : 2607 - 2611
[10] Phosphanyl-substituted phosphaferrocenes as P,P-chelate ligands
Ganter, C
Brassat, L
Ganter, B
[J]. CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (12): : 1771 - 1776

← 1 2 3 →