Nonequilibrium phase diagram of sticky nanotube suspensions

被引:107
作者
Hobbie, E. K. [1 ]
Fry, D. J. [1 ]
机构
[1] NIST, Gaithersburg, MD 20899 USA
关键词
D O I
10.1103/PhysRevLett.97.036101
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We report a universal phase diagram describing the evolution from solidlike networks to flowing nematics for "sticky" nanotube suspensions under an applied shear stress. Although the nanotubes are strongly non-Brownian, we find features characteristic of first-order phase transitions, including a discontinuity in the nematic order parameter at the isotropic-(para)nematic phase boundary. Using simple physical arguments, we account for the shape of the coexistence curves, as well as the dependence of the order parameter on concentration and stress.
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页数:4
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