Azacrown-attached meta-ethynylpyridine polymer: saccharide recognition regulated by supramolecular device

被引：38

作者：

Abe, Hajime ^{[1
]}

Takashima, Shunsuke ^{[1
]}

Yamamoto, Tsuyoshi ^{[1
]}

Inouye, Masahiko ^{[1
]}

机构：

[1] Toyama Univ, Grad Sch Pharmaceut Sci, Toyama 9300194, Japan

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 16期

关键词：

HELICITY INDUCTION; NONCOVALENT INTERACTIONS; CIRCULAR-DICHROISM; SYNTHETIC LECTIN; RECEPTORS; OLIGOMERS; BEARING; MONOSACCHARIDES; AMPLIFICATION; ORGANIZATION;

D O I：

10.1039/b902269d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polymeric synthetic host 2, azacrown-attached 2,6-pyridylene ethynylene polymer, was investigated for its saccharide recognition and the additive effect of triethylene tetramine-trifluoroacetic acid; heteroallosteric effects were observed on the basis of CD and UV/Vis analyses, which indicated saccharide-dependent stabilization and destabilization of helical complexes by the formation of pseudopolyrotaxanes.

引用

页码：2121 / 2123

页数：3

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