Sol-gel derived multiferroic BiFeO3 ceramics with large polarization and weak ferromagnetism

被引:88
作者
Chen, F.
Zhang, Q. F.
Li, J. H.
Qi, Y. J.
Lu, C. J. [1 ]
Chen, X. B.
Ren, X. M.
Zhao, Y.
机构
[1] Hubei Univ, Dept Mat Sci & Engn, Wuhan 430062, Peoples R China
[2] Yangzhou Univ, Coll Phys Sci & Technol, Yangzhou 225002, Peoples R China
[3] SW Jiaotong Univ, Supercond R&D Ctr, Chengdu 610031, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1063/1.2345603
中图分类号
O59 [应用物理学];
学科分类号
摘要
Insulating BiFeO3 ceramics of single perovskite phase were prepared by rapid sintering using sol-gel derived fine powders. The ceramics are dense and consist of grains of 2-6 mu m in diameter. Their leakage current density remains lower than 3.02x10(-4) A/cm(2) under the poling field below 119 kV/cm. The main conduction mechanism from 15 to 119 kV/cm is space-charge-limited current relating to oxygen vacancies. The ceramics exhibit a saturated ferroelectric hysteresis loop with a large remanent polarization (2P(r)=56 mu C/cm(2)) under the applied field of 180 kV/cm. Weak ferromagnetism with remanent magnetization of 1.5x10(-5)mu(B)/Fe is observed at 10 K. (c) 2006 American Institute of Physics.
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页数:3
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