High Mobility Ambipolar Diketopyrrolopyrrole-Based Conjugated Polymer Synthesized Via Direct Arylation Polycondensation

被引：212

作者：

Gao, Yao ^{[1
,2
]}

Zhang, Xiaojie ^{[1
]}

Tian, Hongkun ^{[1
]}

Zhang, Jidong ^{[1
]}

Yan, Donghang ^{[1
]}

Geng, Yanhou ^{[1
,3
,4
]}

Wang, Fosong ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China

[4] Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China

来源：

ADVANCED MATERIALS | 2015年 / 27卷 / 42期

基金：

中国国家自然科学基金;

关键词：

FIELD-EFFECT TRANSISTORS; HIGH-ELECTRON-MOBILITY; HIGH-PERFORMANCE; DIRECT (HETERO)ARYLATION; DIRECT HETEROARYLATION; EFFICIENT APPROACH; BUILDING-BLOCK; SOLAR-CELLS; HIGH HOLE; COPOLYMERS;

D O I：

10.1002/adma.201502896

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A diketopyrrolopyrrole-based conjugated polymer, PDPP-4FTVT, which exhibits ambipolar transport behavior in air with hole and electron mobilities up to 3.40 and 5.86 cm(2) V-1 s(-1), respectively, is synthesized via direct arylation polycondensation. Incorporation of F-atoms in beta-positions of thiophene rings dramatically improves the efficiency of direct arylation polycondensation. [GRAPHICS] .

引用

页码：6753 / +

页数：8

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