Rhodium-catalysed hydroformylation and carbonylation of N-alkenyl-1,3-diaminopropanes

被引:17
作者
Bergmann, DJ [1 ]
Campi, EM [1 ]
Jackson, WR [1 ]
McCubbin, QJ [1 ]
Patti, AF [1 ]
机构
[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA
基金
澳大利亚研究理事会;
关键词
D O I
10.1016/S0040-4020(97)10193-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The rhodium catalysed reactions of N-alkenyl-1,3-diaminopropanes with H-2/CO usually give mixtures of diazabicycloalkanes and aminopropyl lactams. The chemo-and regioselectivity of these reactions are influenced by the choice of ligand and by the ratio of H-2 and CO in the gas mixture and in some cases formation of a single compound can be achieved. (C) 1997 Elsevier Science Ltd.
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页码:17449 / 17460
页数:12
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