Rhodium-catalysed hydroformylation and carbonylation of N-alkenyl-1,3-diaminopropanes

被引：17

作者：

Bergmann, DJ ^{[1
]}

Campi, EM ^{[1
]}

Jackson, WR ^{[1
]}

McCubbin, QJ ^{[1
]}

Patti, AF ^{[1
]}

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

来源：

TETRAHEDRON | 1997年 / 53卷 / 51期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/S0040-4020(97)10193-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rhodium catalysed reactions of N-alkenyl-1,3-diaminopropanes with H-2/CO usually give mixtures of diazabicycloalkanes and aminopropyl lactams. The chemo-and regioselectivity of these reactions are influenced by the choice of ligand and by the ratio of H-2 and CO in the gas mixture and in some cases formation of a single compound can be achieved. (C) 1997 Elsevier Science Ltd.

引用

页码：17449 / 17460

页数：12

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