Rhodium-catalysed hydroformylation and carbonylation of N-alkenyl-1,3-diaminopropanes

被引：17

作者：

Bergmann, DJ ^{[1
]}

Campi, EM ^{[1
]}

Jackson, WR ^{[1
]}

McCubbin, QJ ^{[1
]}

Patti, AF ^{[1
]}

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

来源：

TETRAHEDRON | 1997年 / 53卷 / 51期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/S0040-4020(97)10193-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rhodium catalysed reactions of N-alkenyl-1,3-diaminopropanes with H-2/CO usually give mixtures of diazabicycloalkanes and aminopropyl lactams. The chemo-and regioselectivity of these reactions are influenced by the choice of ligand and by the ratio of H-2 and CO in the gas mixture and in some cases formation of a single compound can be achieved. (C) 1997 Elsevier Science Ltd.

引用

页码：17449 / 17460

页数：12

共 37 条

[31] N-(3-AMINOPROPYL)PYRROLIDIN-2-ONE - A PHYSIOLOGICAL EXCRETORY PRODUCT DERIVING FROM SPERMIDINE
SEILER, N
KNODGEN, B
[J]. INTERNATIONAL JOURNAL OF BIOCHEMISTRY, 1983, 15 (07): : 907 - &
[32] STERIC EFFECTS OF PHOSPHORUS LIGANDS IN ORGANOMETALLIC CHEMISTRY AND HOMOGENEOUS CATALYSIS
TOLMAN, CA
[J]. CHEMICAL REVIEWS, 1977, 77 (03) : 313 - 348
[33] TREASURYWALA AM, 1976, ALDRICHIM ACTA, V9, P22
[34] TURNER NJ, 1995, PREPARATIVE BIOTRANS
[35] UNRUH JD, 1983, HOMOGENEOUS CATALYSI, P309
[36] SYNTHESES OF NITROGEN-HETEROCYCLES BY MEANS OF AMINE-DIRECTED CARBONYLATION AND HYDROCARBONYLATION
ZHANG, Z
OJIMA, I
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 454 (1-2) : 281 - 289
[37] SYNTHESIS OF PYRROLIDINES AND PYRROLIDINONES BY THE RHODIUM COMPLEX CATALYZED CYCLIZATION OF UNSATURATED AMINES
ZHOU, JQ
ALPER, H
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (12) : 3328 - 3331

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