Synthesis of the racemic forms of carbon-carbon double bond locked analogues of strobilurins which are characterized by a 2-arylcyclopropane ring cis-substituted at C-1 by the methyl (E)-3-methoxypropenoate unit

被引：19

作者：

Carpita, A ^{[1
]}

Ribecai, A ^{[1
]}

Rossi, R ^{[1
]}

Stabile, P ^{[1
]}

机构：

[1] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

来源：

TETRAHEDRON | 2002年 / 58卷 / 19期

关键词：

strobilurin; carbon-carbon double bond; methoxy propenoate;

D O I：

10.1016/S0040-4020(02)00334-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The racemic forms of three new carbon-carbon double bond locked analogues of strobilurins, which are characterized by a 2-arylcyclopropane ring cis-substituted at C-1 by the methyl (E)-3-methoxypropenoate unit, have been synthesized according to a strategy which involves the palladiuin-catalyzed synthesis of methyl (E)-3-methoxy-2-[(Z)-2-(aryl)ethenyl]propenoates and their stereospecific cyclopropanation. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：3673 / 3680

页数：8

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