Scattering resonances in the simplest chemical reaction

被引:159
作者
Fernández-Alonso, F
Zare, RN
机构
[1] CNR, Ist Struttura Mat, I-00133 Rome, Italy
[2] Stanford Univ, Dept Chem, Stanford, CA 94305 USA
关键词
transition state; quasibound states; scattering resonance; H+H-2 reaction family; reactive scattering; reaction dynamics;
D O I
10.1146/annurev.physchem.53.091001.094554
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recent studies of state-resolved angular distributions show the participation of reactive scattering resonances in the simplest chemical reaction. This review is intended for those who wish to learn about the state-of-the-art in the study of the H + H-2 reaction family that has made this breakthrough possible. This review is also intended for those who wish to gain insight into the nature of reactive scattering resonances. Following a tour across several fields of physics and chemistry where the concept of resonance has been crucial for the understanding of new phenomena, we offer an operational definition and taxonomy of reactive scattering resonances. We introduce simple intuitive models to illustrate each resonance type. We focus next on the last decade of H + H-2 reaction dynamics. Emphasis is placed on the various experimental approaches that have been applied to the search for resonance behavior in the H + H-2 reaction family. We conclude by sketching the road ahead in the study of H + H-2 reactive scattering resonances.
引用
收藏
页码:67 / 99
页数:37
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