Diastereoselective preparation of chiral-at-metal pentamethylcyclopentadienyl iridium(III) and -rhodium(III) complexes

被引：14

作者：

Loza, ML ^{[1
]}

Parr, J ^{[1
]}

Slawin, AMZ ^{[1
]}

机构：

[1] LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM,LOUGHBOROUGH LE11 3TU,LEICS,ENGLAND

来源：

POLYHEDRON | 1997年 / 16卷 / 13期

关键词：

chiral-at-metal complexes; chiral Schiff base ligands; diastereoselective preparation;

D O I：

10.1016/S0277-5387(96)00592-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between the chiral bidentate Schiff base ligand (S)-N-salicylidene-alpha-phenyethylamine (LH) and [Cp*MCl2](2) (M = Ir, Rh) in the presence of KOt-Bu yields in both cases diastereomerically pure (R)-Cp*M(L)Cl. (C) 1997 Elsevier Science Ltd.

引用

页码：2321 / 2322

页数：2

共 12 条

[1] CHIRALITY CHANGES IN REACTIONS OF ASYMMETRIC MOLYBDENUM COMPLEXES [J].

FALLER, JW ;

SHVO, Y ;

CHAO, K ;

MURRAY, HH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 226 (03) :251-275

[2] CONTROLLING THE REGIOCHEMISTRY OF NUCLEOPHILIC-ATTACK ON UNSYMMETRICAL ALLYL COMPLEXES [J].

FALLER, JW ;

LAMBERT, C ;

MAZZIERI, MR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 383 (1-3) :161-177

[3] ASYMMETRIC SYNTHESES OF (-)-CYCLOOCTEN-3-OL AND (-)-3-DEUTERIOCYCLOOCTENE VIA NUCLEOPHILIC-ATTACK ON (ETA-3-CYCLOOCTENYL)MOLYBDENUM COMPLEXES [J].

FALLER, JW ;

CHAO, KH .

ORGANOMETALLICS, 1984, 3 (06) :927-932

[4] ASYMMETRIC-SYNTHESIS OF (+)-2,2,3-TRIMETHYLHEX-4-ENAL VIA NUCLEOPHILIC-ATTACK ON ETA-3-1,3-DIMETHYLALLYL COMPLEXES OF MOLYBDENUM [J].

FALLER, JW ;

CHAO, KH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (12) :3893-3898

[5]

FALLER JW, 1992, ORGANOMETALLICS, V11, P2762

[6] A ruthenium(II) complex with a C-2-symmetric diphosphine/diamine tetradentate ligand for asymmetric transfer hydrogenation of aromatic ketones [J].

Gao, JX ;

Ikariya, T ;

Noyori, R .

ORGANOMETALLICS, 1996, 15 (04) :1087-1089

[7] Highly stereoselective formation of Cp*IrCl complexes of N,N-dimethylamino acids [J].

Grotjahn, DB ;

Joubran, C ;

Hubbard, JL .

ORGANOMETALLICS, 1996, 15 (04) :1230-1235

[8] ELECTRONIC TUNING OF ASYMMETRIC CATALYSTS [J].

JACOBSEN, EN ;

ZHANG, W ;

GULER, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (17) :6703-6704

[9] SYNTHESIS, PROPERTIES AND CRYSTAL-STRUCTURES OF DIASTEREOMERIC ARENERUTHENIUM(II) CHIRAL SCHIFF-BASE COMPLEXES [J].

MANDAL, SK ;

CHAKRAVARTY, AR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (10) :1627-1633

[10]

Ojima I., 2010, CATALYTIC ASYMMETRIC

← 1 2 →