On the crystallization behavior of cold drawn syndiotactic polypropylene

被引:28
作者
Loos, J [1 ]
Huckert, A [1 ]
Petermann, J [1 ]
机构
[1] UNIV DORTMUND,LEHRSTUHL WERKSTOFFKUNDE,D-44221 DORTMUND,GERMANY
关键词
syndiotactic polypropylene; cold stretching; chain conformation; crystal structure; crystallization behavior;
D O I
10.1007/BF00656632
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The influence of the chain conformation on the crystallization behavior of cold-drawn syndiotactic polypropylene (sPP) has been investigated. The conformational and structural changes depending on drawing conditions and thermal treatments has been observed by x-ray diffraction, infra-red spectroscopy and modulated differential scanning calorimetry. A nucleation and crystal growth model is introduced, which explains the low crystallinity of cold-drawn sPP.
引用
收藏
页码:1006 / 1011
页数:6
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