Carbon nanotube encapsulated fullerenes: a unique class of hybrid materials

被引:219
作者
Smith, BW
Monthioux, M
Luzzi, DE
机构
[1] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
[2] CNRS, CEMES, UPR A8011, F-31055 Toulouse 4, France
基金
美国国家科学基金会;
关键词
D O I
10.1016/S0009-2614(99)00896-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the discovery of elongated fullerene capsules contained within single-wall carbon nanotubes, as well as new findings pertaining to encapsulated, self-assembled chains of C-60. The observed structures comprise a new, complete class of hybrid materials: hemispherically-capped graphene cylinders of various lengths within carbon nanotubes. Short capsules and chains comprised of only a few C-60 molecules spontaneously jump nanometer distances along the axis of the containing tube. A model explaining this behavior is proposed. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:31 / 36
页数:6
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