K6Cd4Sn3Se13:: A polar open-framework compound based on the partially destroyed supertetrahedral [Cd4Sn4Se17]10- cluster

被引：77

作者：

Ding, N ^{[1
]}

Chung, DY ^{[1
]}

Kanatzidis, MG ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 10期

关键词：

D O I：

10.1039/b402686a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

K6Cd4Sn3Se13 forms in superheated water and has a polar open-framework structure that is based on an octahedral topological motif. It forms from the polymerization of a single [Cd4Sn3Se13](6-) cluster which formally derives from a [Cd4Sn4Se17](10-) via elimination of one [SnSe4](4-) anion. K6Cd4Sn3Se13 exhibits facile ion-exchange properties with suitably sized cations.

引用

页码：1170 / 1171

页数：2

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