New azoic dyes containing (1H)-tetrazole and azido group

被引：17

作者：

Dabbagh, AH ^{[1
]}

Mansoori, Y ^{[1
]}

机构：

[1] Isfahan Univ Technol, Coll Chem, Esfahan, Iran

来源：

DYES AND PIGMENTS | 2002年 / 54卷 / 01期

关键词：

azoic dyes; (1H)-tetrazole; diazo coupling; imidoyl azide; nitrene insertion;

D O I：

10.1016/S0143-7208(02)00028-1

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The synthesis of new azoic-dyes containing aryloxytetrazole functional group is reported. The 5-(4'-aminophenoxy)tetrazole was diazotized and coupled with the electron rich aromatic rings. All dyes were characterized by H-1-NMR, C-13-NMR, IR, and UV-vis spectroscopies. They all decomposed above 174 degreesC except dye derived from 4-nitrophenol, which released nitrogen at 86 degreesC to produce tar. These dyes are yellow, brown, or red in color. All dyes are soluble in basic media. The imidoyl azide derivative of dye derived from beta-naphthol produced unexpected hydroxylamine derivative in refluxing 1,4-dioxane. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：37 / 46

页数：10

共 18 条

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