SPIN-STATE CHANGES AND REACTIVITY IN TRANSITION METAL CHEMISTRY: REACTIVITY OF IRON TETRACARBONYL

被引：39

作者：

Besora, Maria ^{[1
,2
]}

Carreon-Macedo, Jose-Luis ^{[1
,2
]}

Cimas, Alvaro ^{[1
,2
]}

Harvey, Jeremy N. ^{[1
,2
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[2] Univ Bristol, Ctr Computat Chem, Bristol BS8 1TS, Avon, England

来源：

ADVANCES IN INORGANIC CHEMISTRY, VOL 61: METAL ION CONTROLLED REACTIVITY | 2009年 / 61卷

基金：

英国工程与自然科学研究理事会;

关键词：

TRANSIENT INFRARED-SPECTROSCOPY; BOND-DISSOCIATION ENERGIES; ULTRAFAST ELECTRON-DIFFRACTION; FORBIDDEN CHEMICAL-REACTIONS; OPEN-SHELL ORGANOMETALLICS; DENSITY-FUNCTIONAL THEORY; EXCIMER-LASER PHOTOLYSIS; GAS-PHASE; OXIDATIVE ADDITION; FLASH-PHOTOLYSIS;

D O I：

10.1016/S0898-8838(09)00210-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[No abstract available]

引用

收藏

页码：573 / 623

页数：51

相关论文

共 151 条

[1] Cobalt-catalyzed cyclotrimerization of alkynes: The answer to the puzzle of parallel reaction pathways [J].

Agenet, Nicolas ;

Gandon, Vincent ;

Vollhardt, K. Peter C. ;

Malacria, Max ;

Aubert, Corinne .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (28) :8860-8871

[2] DYNAMICS OF LIGAND-BINDING TO MYOGLOBIN [J].

AUSTIN, RH ;

BEESON, KW ;

EISENSTEIN, L ;

FRAUENFELDER, H ;

GUNSALUS, IC .

BIOCHEMISTRY, 1975, 14 (24) :5355-5373

[3] A novel facet of carbonyliron-diene photochemistry:: The η4-s-trans isomer of the classical Fe(CO)3(η4-s-cis-1,3-butadiene) discovered by time-resolved IR spectroscopy and theoretically examined by density functional methods [J].

Bachler, V ;

Grevels, FW ;

Kerpen, K ;

Olbrich, G ;

Schaffner, K .

ORGANOMETALLICS, 2003, 22 (08) :1696-1711

[4] The ultrafast photodissociation of Fe(CO)5 in the gas phase [J].

Bañares, L ;

Baumert, T ;

Bergt, M ;

Kiefer, B ;

Gerber, G .

JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (14) :5799-5811

[5] Femtosecond photodissociation dynamics of Fe(CO)(5) in the gas phase [J].

Banares, L ;

Baumert, T ;

Bergt, M ;

Kiefer, B ;

Gerber, G .

CHEMICAL PHYSICS LETTERS, 1997, 267 (1-2) :141-148

[6] AN ABINITIO STUDY OF FE(CO)1, FE(CO)5, AND CR(CO)6 [J].

BARNES, LA ;

ROSI, M ;

BAUSCHLICHER, CW .

JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (03) :2031-2039

[7] MAGNETIC CIRCULAR-DICHROISM EVIDENCE FOR PARAMAGNETISM OF TETRACARBONYLIRON(0) - LOW-TEMPERATURE MATRIX STUDIES [J].

BARTON, TJ ;

GRINTER, R ;

THOMSON, J ;

DAVIES, B ;

POLIAKOFF, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1977, (23) :841-842

[8] A DIRECT METHOD FOR THE LOCATION OF THE LOWEST ENERGY POINT ON A POTENTIAL SURFACE CROSSING [J].

BEARPARK, MJ ;

ROBB, MA ;

SCHLEGEL, HB .

CHEMICAL PHYSICS LETTERS, 1994, 223 (03) :269-274

[9] EVIDENCE FOR THE FORMATION OF FREE 16-ELECTRON SPECIES RATHER THAN SOLVATE COMPLEXES IN THE ULTRAVIOLET-IRRADIATION OF CPCO(CO)(2) IN LIQUEFIED NOBLE-GAS SOLVENTS [J].

BENGALI, AA ;

BERGMAN, RG ;

MOORE, CB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (13) :3879-3880

[10] ACTIVATION OF THE C-H BONDS IN NEOPENTANE AND NEOPENTANE-D(12) BY (ETA(5)-C-5(CH3)(5))RH(CO)(2) - SPECTROSCOPIC AND TEMPORAL RESOLUTION OF RHODIUM-KRYPTON AND RHODIUM-ALKANE COMPLEX INTERMEDIATES [J].

BENGALI, AA ;

SCHULTZ, RH ;

MOORE, CB ;

BERGMAN, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (21) :9585-9589

← 1 2 3 4 5 6 7 8 9 10 →