SPIN-STATE CHANGES AND REACTIVITY IN TRANSITION METAL CHEMISTRY: REACTIVITY OF IRON TETRACARBONYL

被引：39

作者：

Besora, Maria ^{[1
,2
]}

Carreon-Macedo, Jose-Luis ^{[1
,2
]}

Cimas, Alvaro ^{[1
,2
]}

Harvey, Jeremy N. ^{[1
,2
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[2] Univ Bristol, Ctr Computat Chem, Bristol BS8 1TS, Avon, England

来源：

ADVANCES IN INORGANIC CHEMISTRY, VOL 61: METAL ION CONTROLLED REACTIVITY | 2009年 / 61卷

基金：

英国工程与自然科学研究理事会;

关键词：

TRANSIENT INFRARED-SPECTROSCOPY; BOND-DISSOCIATION ENERGIES; ULTRAFAST ELECTRON-DIFFRACTION; FORBIDDEN CHEMICAL-REACTIONS; OPEN-SHELL ORGANOMETALLICS; DENSITY-FUNCTIONAL THEORY; EXCIMER-LASER PHOTOLYSIS; GAS-PHASE; OXIDATIVE ADDITION; FLASH-PHOTOLYSIS;

D O I：

10.1016/S0898-8838(09)00210-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[No abstract available]

引用

收藏

页码：573 / 623

页数：51

相关论文

共 151 条

[91] PHOTOSUBSTITUTION OF 2 IRON PENTACARBONYL COS IN SOLUTION VIA A SINGLE-PHOTON PROCESS - DEPENDENCE ON DISPERSED LIGANDS AND ROLE OF TRIPLET INTERMEDIATES [J].

NAYAK, SK ;

FARRELL, GJ ;

BURKEY, TJ .

INORGANIC CHEMISTRY, 1994, 33 (10) :2236-2242

[92] THE KINETICS OF REACTION OF PHOTOLYTICALLY GENERATED FE(CO)X (X=2,3,4) WITH CO [J].

OUDERKIRK, AJ ;

WEITZ, E .

JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (02) :1089-1091

[93] OBSERVATION OF COORDINATIVELY UNSATURATED INTERMEDIATES FOLLOWING THE PULSED UV PHOTOLYSIS OF FE(CO)5 [J].

OUDERKIRK, AJ ;

WERMER, P ;

SCHULTZ, NL ;

WEITZ, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (10) :3354-3355

[94] Intramolecular coupling reactions of allylic thioesters with diene iron tricarbonyl systems [J].

Pearson, AJ ;

Alimardanov, A ;

Pinkerton, AA ;

Parrish, DA .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (19) :6610-6618

[95] Solvent reorganization controls the rate of proton transfer from neat alcohol solvents to singlet diphenylcarbene [J].

Peon, J ;

Polshakov, D ;

Kohler, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (22) :6428-6438

[96] Molybdenum open-shell organometallics. Spin state changes and pairing energy effects [J].

Poli, R .

ACCOUNTS OF CHEMICAL RESEARCH, 1997, 30 (12) :494-501

[97] Open shell organometallics: a general analysis of their electronic structure and reactivity [J].

Poli, R .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (24) :4291-4304

[98] Spin forbidden chemical reactions of transition metal compounds. New ideas and new computational challenges [J].

Poli, R ;

Harvey, JN .

CHEMICAL SOCIETY REVIEWS, 2003, 32 (01) :1-8

[99]

POLIAKOF.M, 1974, J CHEM SOC DALTON, P2276, DOI 10.1039/dt9740002276

[100] SHEDDING LIGHT ON ORGANOMETALLIC REACTIONS - THE CHARACTERIZATION OF FE(CO)4, A PROTOTYPICAL REACTION INTERMEDIATE [J].

POLIAKOFF, M ;

WEITZ, E .

ACCOUNTS OF CHEMICAL RESEARCH, 1987, 20 (11) :408-414

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