Electrochemistry of Graphene and Related Materials

被引：939

作者：

Ambrosi, Adriano ^{[1
]}

Chua, Chun Kiang ^{[1
]}

Bonanni, Alessandra ^{[1
]}

Pumera, Martin ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

CHEMICAL REVIEWS | 2014年 / 114卷 / 14期

关键词：

NITROGEN-DOPED GRAPHENE; CHEMICAL-VAPOR-DEPOSITION; NANOPARTICLES-DECORATED GRAPHENE; WALLED CARBON NANOTUBES; GRAPHITE-INTERCALATION COMPOUNDS; METAL-FREE ELECTROCATALYSTS; ENHANCED SENSING PLATFORM; OXYGEN REDUCTION REACTION; ION-SELECTIVE ELECTRODES; SENSITIZED SOLAR-CELLS;

D O I：

10.1021/cr500023c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sustainable energy production, environmentally sustainable development, and affordable healthcare are three major challenges of the current global community. Electrochemistry is at the heart of many chemical and biological sensors, as well as energy storage and generation technologies. Electrochemistry utilizes energy in the cleanest possible form, as electricity, to collect or inject electrons through electrodes. Several synthetic routes have been established to prepare graphene, but each one of them, besides possessing different scalability, generates graphene with very different characteristics, which strongly influence its properties. The exfoliation of graphite was also achieved in aqueous solutions with the use of ultrasound in the presence of surfactants such as sodium dodecyl benzenesulfonate (SDBS), sodium cholate (SC), and 1-pyrenecarboxylic acid. The use of ultrasonication is necessary to facilitate the separation of graphene sheets but has a major drawback of breaking them into very small and inhomogeneous flakes.

引用

页码：7150 / 7188

页数：39

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