Resonant X-ray scattering studies of the B2 phase formed by bent-core molecules

被引:16
作者
Cady, A [1 ]
Pindak, R
Caliebe, W
Barois, P
Weissflog, W
Nguyen, HT
Huang, CC
机构
[1] Univ Minnesota, Sch Phys & Astron, Minneapolis, MN 55455 USA
[2] Brookhaven Natl Lab, NSLS, Upton, NY 11973 USA
[3] Univ Bordeaux 1, Ctr Rech Paul Pascal, CNRS, F-33600 Pessac, France
[4] Univ Halle Wittenberg, Inst Phys Chem, D-06108 Halle Saale, Germany
关键词
D O I
10.1080/02678290210156704
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have performed resonant X-ray scattering on two bent-core liquid crystal compounds exhibiting the B2 phase using three sample geometries: free-standing film and two others with free surface arrangements. The results conclusively demonstrate the two-layer orientational periodicity in this phase suggested by optical studies. We have performed the first resonant scattering experiments on liquid crystals at the chlorine K-edge, opening up a new class of compounds for resonant X-ray scattering studies. Furthermore, we have achieved an excellent alignment of the B2 phase with a free surface.
引用
收藏
页码:1101 / 1104
页数:4
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