Review on composite polymer electrolytes for lithium batteries

被引：856

作者：

Stephan, A. Manuel ^{[1
]}

Nahm, K. S. ^{[1
]}

机构：

[1] Chonbuk Natl Univ, Sch Chem Engn & Technol, Chonju 561756, Jeounju, South Korea

来源：

POLYMER | 2006年 / 47卷 / 16期

关键词：

composite electrolytes; inorganic filler; Lewis acid-base theory; POLY(ETHYLENE OXIDE); IONIC-CONDUCTIVITY; TRANSPORT-PROPERTIES; PVDF-HFP; ELECTROCHEMICAL PROPERTIES; INTERFACIAL PROPERTIES; POLY(METHYL METHACRYLATE); SOLID ELECTROLYTES; METAL-ELECTRODE; SOLVENT-FREE;

D O I：

10.1016/j.polymer.2006.05.069

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This paper reviews the state of the art of composite polymer electrolytes (CPE) in view of their electrochemical and physical properties for the applications in lithium batteries. This review mainly encompasses on composite polymer electrolyte hosts namely poly(ethylene oxide) (PEO), poly(acrylonitrile) (PAN), poly(methyl methacrylate) (PMMA) and poly(vinylidene fluoride) (PVdF) studied so far. Also the ionic conductivity, transference number, compatibility and the cycling behavior of poly(vinylidene fluoride-hexafluoro propylene) (PVdF-HFP)-[AlO(OH)](n)-LiPF6/LiClO4 composite electrolytes have been studied and the results are discussed. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：5952 / 5964

页数：13

共 143 条

[1] LI+-CONDUCTIVE SOLID POLYMER ELECTROLYTES WITH LIQUID-LIKE CONDUCTIVITY [J].

ABRAHAM, KM ;

ALAMGIR, M .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (05) :1657-1657

[2] Silicon oxide Nafion composite membranes for proton-exchange membrane fuel cell operation at 80-140° C [J].

Adjemian, KT ;

Lee, SJ ;

Srinivasan, S ;

Benziger, J ;

Bocarsly, AB .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (03) :A256-A261

[3] LI ION CONDUCTIVE ELECTROLYTES BASED ON POLY(VINYL CHLORIDE) [J].

ALAMGIR, M ;

ABRAHAM, KM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (06) :L96-L97

[4] ENTROPY EFFECTS IN IONIC-CONDUCTIVITY [J].

ALMOND, DP ;

WEST, AR .

SOLID STATE IONICS, 1986, 18-9 :1105-1109

[5] Investigation on the stability of the lithium-polymer electrolyte interface [J].

Appetecchi, GB ;

Scaccia, S ;

Passerini, S .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (12) :4448-4452

[6] Hot-pressed, solvent-free, nanocomposite, PEO-based electrolyte membranes II.: All solid-state Li/LiFePO4 polymer batteries [J].

Appetecchi, GB ;

Hassoun, J ;

Scrosati, B ;

Croce, F ;

Cassel, F ;

Salomon, M .

JOURNAL OF POWER SOURCES, 2003, 124 (01) :246-253

[7] KINETICS AND STABILITY OF THE LITHIUM ELECTRODE IN POLY(METHYLMETHACRYLATE)-BASED GEL ELECTROLYTES [J].

APPETECCHI, GB ;

CROCE, F ;

SCROSATI, B .

ELECTROCHIMICA ACTA, 1995, 40 (08) :991-997

[8] Transport and interfacial properties of composite polymer electrolytes [J].

Appetecchi, GB ;

Croce, F ;

Persi, L ;

Ronci, F ;

Scrosati, B .

ELECTROCHIMICA ACTA, 2000, 45 (8-9) :1481-1490

[9] Composite polymer electrolytes with improved lithium metal electrode interfacial properties - II. Application in rechargeable batteries [J].

Appetecchi, GB ;

Croce, F ;

Mastragostino, M ;

Scrosati, B ;

Soavi, F ;

Zanelli, A .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (12) :4133-4135

[10] Composite polymer electrolytes with improved lithium metal electrode interfacial properties - I. Electrochemical properties of dry PEO-LiX systems [J].

Appetecchi, GB ;

Croce, F ;

Dautzenberg, G ;

Mastragostino, M ;

Ronci, F ;

Scrosati, B ;

Soavi, F ;

Zanelli, A ;

Alessandrini, F ;

Prosini, PP .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (12) :4126-4132

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