Review on composite polymer electrolytes for lithium batteries

被引：856

作者：

Stephan, A. Manuel ^{[1
]}

Nahm, K. S. ^{[1
]}

机构：

[1] Chonbuk Natl Univ, Sch Chem Engn & Technol, Chonju 561756, Jeounju, South Korea

来源：

POLYMER | 2006年 / 47卷 / 16期

关键词：

composite electrolytes; inorganic filler; Lewis acid-base theory; POLY(ETHYLENE OXIDE); IONIC-CONDUCTIVITY; TRANSPORT-PROPERTIES; PVDF-HFP; ELECTROCHEMICAL PROPERTIES; INTERFACIAL PROPERTIES; POLY(METHYL METHACRYLATE); SOLID ELECTROLYTES; METAL-ELECTRODE; SOLVENT-FREE;

D O I：

10.1016/j.polymer.2006.05.069

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This paper reviews the state of the art of composite polymer electrolytes (CPE) in view of their electrochemical and physical properties for the applications in lithium batteries. This review mainly encompasses on composite polymer electrolyte hosts namely poly(ethylene oxide) (PEO), poly(acrylonitrile) (PAN), poly(methyl methacrylate) (PMMA) and poly(vinylidene fluoride) (PVdF) studied so far. Also the ionic conductivity, transference number, compatibility and the cycling behavior of poly(vinylidene fluoride-hexafluoro propylene) (PVdF-HFP)-[AlO(OH)](n)-LiPF6/LiClO4 composite electrolytes have been studied and the results are discussed. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：5952 / 5964

页数：13

共 143 条

[41] Ion-transport phenomena in concentrated PEO-based composite polymer electrolytes [J].

Golodnitsky, D ;

Ardel, G ;

Peled, E .

SOLID STATE IONICS, 2002, 147 (1-2) :141-155

[42] Conduction mechanisms in concentrated LiI polyethylene oxide Al2O3-based solid electrolytes [J].

Golodnitsky, D ;

Ardel, G ;

Strauss, E ;

Peled, E ;

Lareah, Y ;

Rosenberg, Y .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (10) :3484-3491

[43] NMR, DSC, AND CONDUCTIVITY STUDY OF A POLY(ETHYLENE OXIDE) COMPLEX ELECTROLYTE - PEO(LIC104)X [J].

GORECKI, W ;

ANDREANI, R ;

BERTHIER, C ;

ARMAND, M ;

MALI, M ;

ROOS, J ;

BRINKMANN, D .

SOLID STATE IONICS, 1986, 18-9 (pt 1) :295-299

[44]

Gray F.M., 1997, Polymer Electrolytes Royal Soc. Chem. Cambridge, V1st

[45]

Gray F.M., 1991, SOLID POLYM ELECTROL

[46] POLY(ETHYLENE OXIDE) - LICF3SO3 - POLYSTYRENE ELECTROLYTE SYSTEMS [J].

GRAY, FM ;

MACCALLUM, JR ;

VINCENT, CA .

SOLID STATE IONICS, 1986, 18-9 :282-286

[47] IMPROVED CAPACITY RETENTION IN RECHARGEABLE 4V LITHIUM LITHIUM MANGANESE OXIDE (SPINEL) CELLS [J].

GUMMOW, RJ ;

DEKOCK, A ;

THACKERAY, MM .

SOLID STATE IONICS, 1994, 69 (01) :59-67

[48]

HUANG H, 1992, ELECTROCHIM ACTA, V37, P1671

[49]

IIJIMA T, 1985, DENKI KAGAKU, V53, P619

[50] XPS study of lithium surface after contact with lithium-salt doped polymer electrolytes [J].

Ismail, I ;

Noda, A ;

Nishimoto, A ;

Watanabe, M .

ELECTROCHIMICA ACTA, 2001, 46 (10-11) :1595-1603

← 1 2 3 4 5 6 7 8 9 10 →