Facile reaction of o-carboranyllithium reagents with functionalized alkyl halides

被引：11

作者：

Cai, JP

Nemoto, H

Singaram, B

Yamamoto, Y

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 98077,JAPAN

[2] UNIV CALIF SANTA CRUZ,DEPT CHEM & BIOCHEM,SANTA CRUZ,CA 95064

[3] OKAZAKI NATL RES INST,INST MOLEC SCI,OKAZAKI,AICHI 444,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 19期

关键词：

D O I：

10.1016/0040-4039(96)00552-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Unlike the normal organolithium reagents, o-carboranyllthium derivatives can tolerate many functional groups, such as ketones, nitriles and esters. This chemoselectivity is utilized in synthesizing a wide variety of o-carborane derivatives confirming functional groups by reacting o-carboranyllithium reagents with functionalized alkyl halides, such as ethyl bromoacetate. (C) 1996 Elsevier Science Ltd

引用

页码：3383 / 3386

页数：4

共 14 条

[1] DICARBA-CLOSO-DODECABORANES C2B10H12 AND THEIR DERIVATIVES [J].