Thermal degradation of PE and PS mixed with ABS-Br and debromination of pyrolysis oil by Fe- and Ca-based catalysts

被引：68

作者：

Brebu, M

Bhaskar, T

Murai, K

Muto, A

Sakata, Y

Uddin, MA

机构：

[1] Okayama Univ, Dept Appl Chem, Fac Engn, Okayama 7008530, Japan

[2] Univ New S Wales, Sch Chem Engn & Ind Chem, Sydney, NSW, Australia

[3] Petru Poni Inst Macromol Chem, Iasi 700487, Romania

来源：

POLYMER DEGRADATION AND STABILITY | 2004年 / 84卷 / 03期

关键词：

PE/ABS-Br; PS/ABS-Br; catalytic decomposition carbon composite; debromination;

D O I：

10.1016/j.polymdegradstab.2004.02.003

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymer mixtures containing 8 g of high density polyethylene (PE) or polystyrene (PS) and 2 g of acrylonitrile-butadiene-styrene copolymer containing a polybrominated epoxy type flame retardant (ABS-Br) were thermally degraded at 450degreesC. FeOOH and two carbon composites based on iron (Fe-C) and calcium (Ca-C) were used for catalytic decomposition and their effect on the bromine and nitrogen amount and distribution in pyrolysis oil was determined by GC-AED analysis. It was found that iron-based catalysts removed bromine from pyrolysis oil and decreased the nitrogen amount converting nitrile compounds into ammonia. Calcium carbon composite had lower effect especially on the pyrolysis of PS/ABS-Br mixture. These liquid products can be used as fuel oil or feedstock in petroleum refinery. (C) 2004 Elsevier Ltd. All rights reserved.

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页码：459 / 467

页数：9

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